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Copper and copper alloys have been recycled for hundreds
of years. Early on, man learned that if newly mined
copper ore was not available, copper objects could be
melted and cast into new objects. During wartime,
weapons were made from recycled decorative and household
goods, and even bells. After the war they were turned
back into non-war related products. Prior to the
American Revolutionary war, all American made copper and
copper alloy products were made with recycled metal
because the British mandated that all copper ore be sent
to England for processing. Since those early days
recycled copper has remained a major source of copper in
the United States, accounting for almost half of the
copper produced and sold each year. |
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The Scrap Flow
Copper Scrap
Today, the process of transforming unalloyed copper
scrap into new copper products begins with purchasing
copper scrap from a national network of scrap processors
and brokers. No. 1 scrap consists of clean, unalloyed,
and uncoated copper solids,clippings, punchings, bus
bars, commutator segments, clean pipe and tubing. No.2
copper scrap is the same but may include oxidized or
coated/plated pieces including oxidized or coated copper
wire free of excessive oxidation.
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When copper scrap is received for recycling it is
visually inspected and graded, and analyzed chemically
if necessary. Loose scrap is baled and stored until
needed. No. 1 scrap material is directly melted and in
some cases brought to higher purity while molten (fire
refined). Chemical analysis checks the purity level of
the copper when the charge is fully melted, and the
molten copper is deoxidized and cast into an
intermediate shape (billets, cakes, ingots) for further
processing. Number 2 scrap is usually electrolytically
refined to attain the desired purity level. But first
the scrap material is perhaps fire refined somewhat,
melted and cast into anodes. These anodes are the raw
material used in cathode production. The anodes are then
electrolytically refined, essentially an electroplating
process in which the anode is electrolytically dissolved
into a bath of sulfuric acid and then electroplated out
of the solution onto a stainless steel sheet. Thin
sheets of pure copper are pulled off the stainless sheet
and placed between anode plates in other electrolytic
cells where further electroplating transforms these
anodes into 99.98% pure copper which builds up into
cathodes as it plates out on the thin pure copper
starter sheets.
Copper alloys are also recycled. Alloy scrap has to be
segregated, kept clean and identified so that the
alloying elements and impurity content of each batch are
known. Scrap of unknown composition may be melted and
analyzed to determine its composition. Alloy recycling
is then accomplished by melting together batches of
scrap of known composition, perhaps along with virgin
material, carefully compounded so that the recycled
material has the alloy composition desired.
Users of Scrap :
The only significant drawback to using recycled copper
is that it may contain trace impurities that negatively
impact its properties. As a result, some applications
require newly mined, or primary copper or scrap copper
that has been re-refined or re-smelted and re-refined.
The most important of these applications is high
conductivity wire.
Ingot producers and large captive foundries have
traditionally been large consumers of used copper/brass
automotive radiators. This material conveniently
provides copper, zinc, tin and lead units in relative
amounts that are ideal for production of the
approximately 100,000 short tons of red-brass and
semi-red brass alloy ingots. About half of this ingot
material is used for plumbing valves and fittings in the
U.S., a distinctly different picture than in Europe
where yellow brass (copper-zinc alloys) predominates in
plumbing products.
The radiator to red brass transformation has been an
economically driven and environmentally sound recycling
of valuable materials. No detailed statistics on the
contribution that radiator scrap makes to the 250,000
tons of scrap consumed for cast products exist, but
discussion with ingot manufacturers indicates that over
recent years radiators have accounted for about 50% of
the US production of red and semi-red brass alloys.
About 50,000 tons of radiators per year are recycled by
ingot producers. The plumbing alloys themselves, as both
post consumer product and prompt scrap returns, have
also been a significant contribution to the ingot
producers' incoming material.
Copper scrap,
namely the following:
Copper scrap, namely the following:
ISRI Code Barley, Berry and Birch - Copper wire scrap
covered by HS Code 7404 00 12
ISRI Code Candy - Heavy copper scrap covered by HS
Code 7404 00 12
ISRI Code Cliff - Unalloyed copper scrap covered by HS
7404 00 12 Code
ISRI Code Clove, Cobra and Cocoa - Copper wire
nodules scrap covered by by HS Code 7404 00 12
ISRI Code
Dream - Light copper scrap covered by HS Code
7404 00 12
ISRI Code Palms - Muntz metal tubes covered by HS
Code 7404 00 12
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